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Though I don't have any hard values for input impedance since they aren't listed in the spec, it would seem dependent on which ADC you select. SAR ADC1 has a built-in LNA, so you should be able to configure it as a unity gain amplifier which as I'm sure you know will give you extremely low input impedance. The other ADCs don't have this feature so I presume the input impedance will be high like most microcontrollers. If you don't want jitter or slow sample issues, then you need to either use the integrated LNA or use an external op amp to feed the ADC.
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