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ESP32-S3 hast Marketing Status: Samples
select left ESP32-S3
you see right one item - ESP32-S3 - and the Marketing Status "Sample" -
select it right - you see then on top new updated Diagram which is in the Prerelease V0.3.1 also the Specs
So you can request with your usecase Samples and Pre Release Datasheet.
Also there is an engineering sample DevKit named "Addax" - exactly "ESP32-S3-Addax-1 V1.0" an Devkit with ESP32-S3 (beta2) "Marlin_9_1B" with 8MB PSRAM and 8MB Flash spotted and more.
You find few further infos also in the parallel post i did here, cause it was over the spotted Addax DevKit. Also you can find a pre-release datasheet in the post there linked.
best wishes
rudi